Positions are available for
highly motivated undergraduates, graduates, and highly talented postdoctral researchers.
Catalysis & Methodology & Radiochemistry
To develop various organic transformations and to find methods to access 18F‐labeled PET tracers more practically
READ MORETransition Metal Chemistry for Activation of Small Molecules
To synthesize well‐defined inorganic complexes which catalyze small molecules highly efficiently for useful chemical feedstocks
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N-Heterocyclic Carbene Nitric Oxide Radicals
J. Park, H. Song, Y. Kim, B. Eun, Y. Kim, D. Y. Bae, S. Park, Y. M. Rhee, W. J. Kim, K. Kim, E. Lee.*
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N-Heterocyclic carbene-stabilized nitric oxide radicals were prepared by direct addition of nitric oxide to two NHCs in solution phase. The nitric oxide moiety in the solid compounds obtained can be thermally transferred to another NHC, suggesting potential applications to NO delivery.
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Triazenyl Radicals Stabilized by N-Heterocyclic Carbenes
J. Back, J. Park, Y. Kim, H. Kang, Y. Kim, M. J. Park, K. Kim, E. Lee.*
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The synthesis and full characterization of the first NHC-stabilized triazenyl radicals were reported. These radicals were obtained by one-electron reduction of the corresponding triazenyl cations with potassium metal.